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Electrochemical nitric oxide sensor preparation: a comparison of two electrochemical methods of electrode surface modification

Authors: 
Nizam Diab, Joshua Oni, Wolfgang Schuhmann
Journal Name: 
Bioelectrochemistry
Volume: 
66
Issue: 
2
Pages From: 
105
To: 
110
Date: 
Sunday, May 1, 2005
Abstract: 
Platinum electrodes modified with Mn(II) 5-(N-(8-pyrrole-yl-3,6-dioxa-1-aminooctane)phenylamide-10,15,20-trimethoxyphenylporphyrin (Mn(II)triOMeTCPPyP) using multi-sweep cyclic voltammetry and differential pulse amperometry were evaluated as electrocatalytic surfaces for the oxidation of nitric oxide. The electrodes modified using the pulse amperometric approach were more sensitive towards the detection of nitric oxide. The increased sensitivity led to the attainment of a wider linear dynamic range for the quantification of nitric oxide